Isotopic Fractionation of Sulfur in Carbonyl Sulfide by Carbonyl Sulfide Hydrolase of <i>Thiobacillus thioparus</i> THI115

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Isotopic Fractionation of Sulfur in Carbonyl Sulfide by Carbonyl Sulfide Hydrolase of Thiobacillus thioparus THI115

Carbonyl sulfide (COS) is one of the major sources of stratospheric sulfate aerosols, which affect the global radiation balance and ozone depletion. COS-degrading microorganisms are ubiquitous in soil and important for the global flux of COS. We examined the sulfur isotopic fractionation during the enzymatic degradation of COS by carbonyl sulfide hydrolase (COSase) from Thiobacillus thioparus T...

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Carbonyl sulfide-mediated prebiotic formation of peptides.

Almost all discussions of prebiotic chemistry assume that amino acids, nucleotides, and possibly other monomers were first formed on the Earth or brought to it in comets and meteorites, and then condensed nonenzymatically to form oligomeric products. However, attempts to demonstrate plausibly prebiotic polymerization reactions have met with limited success. We show that carbonyl sulfide (COS), ...

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Carbonyl sulfide: an inhibitor of inorganic carbon transport in cyanobacteria.

Cells of a high CO(2)-requiring mutant (E(1)) and wild type of Synechococcus PCC7942 were incubated with COS in the light, then suspended in COS-free medium and their CO(2) exchange was measured using an open gas-analysis system under the conditions where photosynthetic CO(2) fixation is inhibited. When the suspension of cells untreated with COS was illuminated, the rate of CO(2) uptake was hig...

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ژورنال

عنوان ژورنال: Microbes and environments

سال: 2017

ISSN: 1342-6311,1347-4405

DOI: 10.1264/jsme2.me17130